GRACO INC. -- THROAT SEAL LIQUID (TSL) -- -
<pre>===================== Product Identification =====================
Product ID:THROAT SEAL LIQUID (TSL)
MSDS Date:09/01/1997
FSC:NIIN:Submitter:D DG
Status Code:A
=== Responsible Party ===
Company Name:GRACO INC.
Address:60-11TH AVE NE
Box:1441
City:MINNEAPOLIS
State:MN
ZIP:55440
Info Phone Num:303-623-5716
Emergency Phone Num:303-623-6516
Chemtrec Ind/Phone:(800)424-9300
CAGE:25980
=== Contractor Identification ===
Company Name:GRACO INC.
Address:4050 OLSON MEMORIAL HWY
Box:1441
City:MINNEAPOLIS
State:MN
ZIP:55440-1441
Country:US
Phone:612-623-6646
CAGE:25980
============= Composition/Information on Ingredients =============
Ingred Name:TRICRESYL PHOSPHATE
CAS:1330-78-5
RTECS #:TD0175000
= Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL-LD50 >5000 MG/KG (RAT)(FMC 191-1211
Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MINIMALLY IRRITATING TO THE EYES
IF MISTED. SKIN: NO SIGNIFICANT HEALTH HAZARDS IDENTIFIED.
INHALATION: MAY BE IRRITATING TO THE RESPIRATORY SYSTEM IF MISTED.
INGESTION: SWALLOWING LARGE QUAN TITIES MAY CAUSE NEUROLOGICAL
DISTURBANCES WHICH MAY PROGRESS TO DELAYED NEUROTOXICITY
CHARACTERIZED BY ATAXIA AND TREMORS.
Explanation of Carcinogenicity:TRICRESYL PHOSPHATE NOT FOUND IN NTP,
IARC OR OSHA LISTS.
======================= First Aid Measures =======================
First Aid:EYES: WASH EYES WITH WATER FOR 15 MIN WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: WASH
EXPOSED SKIN WITH SOAP AND WATER. INHALATION: EFFECTS FROM
INHALATION ARE N OT EXPECTED, HOWEVER IF THEY OCCUR, MOVE THE
VICTIM TO FRESH AIR AND GET MEDICAL ATTENTION AS NECESSARY.
INGESTION: CONTACT THE LOCAL POISON CONTROL CENTER OR A PHYSICIAN
FOR INSTRUCTIONS. DO NOT IND UCE VOMITING OR GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS INDIVIDUAL.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL,
MULTIPURPOSE FOAM.
Fire Fighting Procedures:IN FIRES INVOLVING THIS MATERIAL, WEAR FULL
PROTECTIVE CLOTHING, INCLUDING SELF-CONTAINED BREATHING APPARATUS
(SCBA).
Unusual Fire/Explosion Hazard:SLIGHTLY COMBUSTIBLE; NO EXPLOSION
HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:<GALLON: ABSORB SPILLED MATERIAL WITH
COMMERCIAL OIL ABSORBENT MATERIAL. SHOVEL ABSORBED SPILL INTO
CONTAINERS FOR DISPOSAL. >GALLON: KEEP MATERIAL OUT OF STREAMS AND
SEWERS. ABSORB SPILLED MATERIAL ON COMMERCIAL OIL ABSORBENT OR
SAND. USE ABSORBENT TO DIKE SPILL AREA IF NECESSARY TO PREVENT
SPREAD. SHOVEL ABSORBED MATERIAL INTO A DOT APPROVED CONTAINER AND
DISPOSE.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: AVOID GENERATION OF MISTS IN
OCCUPIED AREAS. STORAGE: STORE IN CLOSED CONTAINERS WHEN NOT IN
USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN HIGH TEMPERATURE APPLICATIONS OR WHERE
EXPOSURE TO MISTING IS EXPECTED, USE NIOSH APPROVED ORGANIC VAPOR
RESPIRATOR WITH MIST PREFILTER. USE SELF-CONTAINED BREATHING
APPARATUS IN EMERGENCY SITUATIO NS.
Ventilation:DILUTION (GENERAL) VENTILATION IS NORMALLY SUFFICIENT IF
HANDLED AT ROOM TEMPERATURE. AT HIGH TEMP OR IF MISTING IS
ANTICIPATED, USE LOCAL EXHAUST VENTILATION
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:WEAR APRON, IMPERVIOUS CLOTHING AND RUBBER
BOOTS IF SPLASHING IS EXPECTED.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:V5
Boiling Pt:>241.C, 465.8F
B.P. Text:241-255C
Melt/Freeze Pt:<-40.C, -40.F
Vapor Pres:0.033 @ 150C
Spec Gravity:1.16 - 1.75
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR LIQUID, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE IDENTIFIED
Hazardous Decomposition Products:UNDER FIRE CONDITIONS, PHOSPHOROUS
OXIDES MAY FORM. NO DECOMPOSITION IN NORMAL USE.
=================== Toxicological Information ===================
Toxicological Information:TCP HAS LOW ACUTE ORAL & DERMAL TOXICITY & IS
NOT IRRITATING TO THE SKIN. TCP IS MINIMALLY IRRITATING TO THE EYES
& MAY BE IRRITATING TO THE RESPIRATORY SYSTEM & MUCOUS MEMBRANES.
BREATHING OR SWALLOW ING LARGE QUANTITIES MAY CAUSE NEUROLOGICAL
DISTURBANCE WHICH MAY PROGRESS TO DELAYED NEUROTOXICITY
CHARACTERIZED BY ATAXIA & TREMORS.
===================== Ecological Information =====================
Ecological:96 HR LC50 (RAINBOW TROUT) = 0.75 (0.54 - 1.04) MG/L; 96 HR
LC50 (FATHEAD MINNOW) = 100 MG/L. 48 HR LC50 (DAPHNIA MAGNA) = 0.27
(0.21 - 0.33) MG/L; 96 HR LC50 (BLUEGILL SUNFISH) = 7000 MG/L.
BIODEGRA TION IS EXPECTED IN SOILS. AQUEOUS HYDROLYSIS CAN
CONTRIBUTE TO SOIL DEGRADATION, EXPECIALLY IN ALKALINE SOILS (3-DAY
HALF LIFE AT PH 9). WILL BIODEGRADE IN AEROBIC WATERS WITH
HALF-LIFE ON THE ORDER OF SEVERAL DAYS OR LESS.
==================== Disposal Considerations ====================
Waste Disposal Methods:AN ACCEPTABLE METHOD OF DISPOSAL IS TO BURN IN
AN INCINERATOR IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL
REQUIREMENTS. APPROPRIATE REGULATORY AGENCIES SHOULD BE CONTACTED
PRIOR TO DISPOSAL.
=================== MSDS Transport Information ===================
Transport Information:IMO/IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCES,
LIQUID, NOS (TRICRESYL PHOSPHATE, LESS THAN 1% ORTHO-ISOMER). AIR:
NON-BULK SHIPMENTS NOT REGULATED. US DOT: NOT REGULATED IN
NON-BULK SHIPMENT QUANT ITIES.
===================== Regulatory Information =====================
SARA Title III Information:NOT LISTED ON SARA TITLE III SECTIONS 302
EXTREMELY HAZARDOUS SUBSTANCES, 311/312 OR 313. DELAYED (CHRONIC)
HEALTH HAZARD SARA SEC. 311/312 HAZARDOUS CATEGORY.
Federal Regulatory Information:NOT LISTED ON THE CERCLA SECTIONS
102A/103 HAZARDOUS SUBSTANCES (40 CFR PART 302.4) INVENTORY. OSHA
HAZARD COMMUNICATION STANDARD: DELAYED (CHRONIC) HEALTH HAZARD.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.